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Scope and Mechanism of Deprotection of Carboxylic Esters by Bis(tributyltin) Oxide

✍ Scribed by Salomon, Claudio J.; Mata, Ernesto G.; Mascaretti, Oreste A.

Book ID
118245449
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
993 KB
Volume
59
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Bis (tributyltin) oxide. A mild, neutral
Bis (tributyltin) oxide. A mild, neutral and selective reagent for cleavage of esters. Scope and limitation of the reaction
✍ Claudio J. Salomon; Ernesto G. Mata; Oreste A. Mascaretti πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 309 KB

Bis(tributyltin)oxide acts as a mild, neutral and chemoselective ester cleavage reagent for a variety of carboxylic esters with good to excellent yields. The acyl-oxygen cleavage mechanism of (-)-(1 R) menthyl acetate is discussed.