𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mild deprotection of steroid esters by Bis(tributyltin)oxide

✍ Scribed by Marina G. Pérez; Marta S. Maier

Book ID
103408631
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
201 KB
Volume
36
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Bis (tributyltin) oxide. A mild, neutral
Bis (tributyltin) oxide. A mild, neutral and selective reagent for cleavage of esters. Scope and limitation of the reaction
✍ Claudio J. Salomon; Ernesto G. Mata; Oreste A. Mascaretti 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 309 KB

Bis(tributyltin)oxide acts as a mild, neutral and chemoselective ester cleavage reagent for a variety of carboxylic esters with good to excellent yields. The acyl-oxygen cleavage mechanism of (-)-(1 R) menthyl acetate is discussed.