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Bis (tributyltin) oxide. A mild, neutral and selective reagent for cleavage of esters. Scope and limitation of the reaction

โœ Scribed by Claudio J. Salomon; Ernesto G. Mata; Oreste A. Mascaretti

Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
309 KB
Volume
32
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Bis(tributyltin)oxide acts as a mild, neutral and chemoselective ester cleavage reagent for a variety of carboxylic esters with good to excellent yields. The acyl-oxygen cleavage mechanism of (-)-(1 R) menthyl acetate is discussed.

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