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ChemInform Abstract: Scope and Mechanism of Deprotection of Carboxylic Esters by Bis( tributyltin) Oxide.

✍ Scribed by C. J. SALOMON; E. G. MATA; O. A. MASCARETTI


Book ID
112023303
Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
26
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


Bis (tributyltin) oxide. A mild, neutral
✍ Claudio J. Salomon; Ernesto G. Mata; Oreste A. Mascaretti πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 309 KB

Bis(tributyltin)oxide acts as a mild, neutral and chemoselective ester cleavage reagent for a variety of carboxylic esters with good to excellent yields. The acyl-oxygen cleavage mechanism of (-)-(1 R) menthyl acetate is discussed.