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Ru-Catalyzed Asymmetric Hydrogenation of Racemic Aldehydes via Dynamic Kinetic Resolution: Efficient Synthesis of Optically Active Primary Alcohols.

✍ Scribed by Jian-Hua Xie; Zhang-Tao Zhou; Wei-Ling Kong; Qi-Lin Zhou

Publisher
John Wiley and Sons
Year
2007
Weight
20 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Enantioselective Synthesis of Chiral Ξ²-Aryloxy Alcohols by Asymmetric Hydrogenation of Ξ±-Aryloxy Aldehydes via Dynamic Kinetic Resolution
✍ Zhang-Tao Zhou; Jian-Hua Xie; Qi-Lin Zhou πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 174 KB πŸ‘ 1 views

## Abstract magnified image A catalytic enantioselective hydrogenation of racemic α‐aryloxy aldehydes __via__ dynamic kinetic resolution has been developed by using (diamine)(spirodiphosphine)ruthenium(II) chloride [RuCl~2~(SDPs)(diamine)] catalysts. Employing this new reaction system a variety of