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Enantioselective Synthesis of Chiral β-Aryloxy Alcohols by Ruthenium-Catalyzed Ketone Hydrogenation via Dynamic Kinetic Resolution (DKR)

✍ Scribed by Wen-Ju Bai; Jian-Hua Xie; Ya-Li Li; Sheng Liu; Qi-Lin Zhou

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
185 KB
Volume
352
Category
Article
ISSN
1615-4150

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Enantioselective Synthesis of Chiral β-A
Enantioselective Synthesis of Chiral β-Aryloxy Alcohols by Asymmetric Hydrogenation of α-Aryloxy Aldehydes via Dynamic Kinetic Resolution
✍ Zhang-Tao Zhou; Jian-Hua Xie; Qi-Lin Zhou 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB

## Abstract magnified image A catalytic enantioselective hydrogenation of racemic α‐aryloxy aldehydes __via__ dynamic kinetic resolution has been developed by using (diamine)(spirodiphosphine)ruthenium(II) chloride [RuCl~2~(SDPs)(diamine)] catalysts. Employing this new reaction system a variety of