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Dynamic Kinetic Resolution Allows a Highly Enantioselective Synthesis of cis-α-Aminocycloalkanols by Ruthenium-Catalyzed Asymmetric Hydrogenation

✍ Scribed by Sheng Liu; Jian-Hua Xie; Li-Xin Wang; Qi-Lin Zhou


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
108 KB
Volume
119
Category
Article
ISSN
0044-8249

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## Abstract magnified image A catalytic enantioselective hydrogenation of racemic α‐aryloxy aldehydes __via__ dynamic kinetic resolution has been developed by using (diamine)(spirodiphosphine)ruthenium(II) chloride [RuCl~2~(SDPs)(diamine)] catalysts. Employing this new reaction system a variety of