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ChemInform Abstract: Enantioselective Synthesis of Chiral β-Aryloxy Alcohols by Ruthenium-Catalyzed Ketone Hydrogenation via Dynamic Kinetic Resolution (DKR).

✍ Scribed by Wen-Ju Bai; Jian-Hua Xie; Ya-Li Li; Sheng Liu; Qi-Lin Zhou

Publisher: John Wiley and Sons
Year: 2010
Weight: 65 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201022065

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Enantioselective Synthesis of β-Dibenzylamino Alcohols via a Dynamic Kinetic Resolution of α-Halo Acids. -The title compounds (IV), precursors of synthetically important Reetz aldehydes, are prepared by highly diastereoselective amination of α-bromo esters (I). The high yields obtained in this amin