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ChemInform Abstract: Enantioselective Synthesis of Chiral β-Aryloxy Alcohols by Asymmetric Hydrogenation of α-Aryloxy Aldehydes via Dynamic Kinetic Resolution.

✍ Scribed by Zhang-Tao Zhou; Jian-Hua Xie; Qi-Lin Zhou

Publisher
John Wiley and Sons
Year
2009
Weight
30 KB
Volume
40
Category
Article
ISSN
0931-7597

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Enantioselective Synthesis of Chiral β-A
Enantioselective Synthesis of Chiral β-Aryloxy Alcohols by Asymmetric Hydrogenation of α-Aryloxy Aldehydes via Dynamic Kinetic Resolution
✍ Zhang-Tao Zhou; Jian-Hua Xie; Qi-Lin Zhou 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB 👁 1 views

## Abstract magnified image A catalytic enantioselective hydrogenation of racemic α‐aryloxy aldehydes __via__ dynamic kinetic resolution has been developed by using (diamine)(spirodiphosphine)ruthenium(II) chloride [RuCl~2~(SDPs)(diamine)] catalysts. Employing this new reaction system a variety of

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Enantioselective Synthesis of β-Dibenzylamino Alcohols via a Dynamic Kinetic Resolution of α-Halo Acids. -The title compounds (IV), precursors of synthetically important Reetz aldehydes, are prepared by highly diastereoselective amination of α-bromo esters (I). The high yields obtained in this amin