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Removal of methoxyethoxymethyl ethers with trimethylsilyl chloride-sodium iodide

✍ Scribed by James H. Rigby; JoAnn Zbur Wilson

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
176 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

suumlary: Trimethylsilyl chloride-sodium iodide has been used for the mild removal Of methoxyethoxymethyl ethers.

πŸ“œ SIMILAR VOLUMES

Selective cleavage of ethers by sodium i
Selective cleavage of ethers by sodium iodide-acyl chloride
✍ Akira Oku; Toshiro Harada; Kazuhiro Kita πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 232 KB

Cyclic and acyclic ethers are regioselectively cleaved at less substituted a-carbon-oxygen bond in the absence of Lewis acid by the reagent system of sodium iodide and acyl chlorides.

Reductive transformations with trimethyl
Reductive transformations with trimethylsilyl chloride-sodium iodide. A new synthesis of 4H-1,3-oxazines
✍ Eugene Ghera; Rakesh Maurya; Alfred Hassner πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 248 KB

1-Arylalkenes and l-arylalkanols are reduced to arylallcanes on heating with trimethylsilyl chloride/sodium iodide in CH&N. Under similar conditions enones, dialkylated in the Bposition of the double bond, give BH-1,3-oxazines.

tert-Butyl Ethers: Renaissance of an Alc
tert-Butyl Ethers: Renaissance of an Alcohol Protecting Group. Facile Cleavage with Cerium(III) Chloride/Sodium Iodide.
✍ Giuseppe Bartoli; Marcella Bosco; Armando Carlone; Manuela Locatelli; Enrico Mar πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons βš– 32 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

tert-Butyl Ethers: Renaissance of an Alc
tert-Butyl Ethers: Renaissance of an Alcohol Protecting Group. Facile Cleavage with Cerium(III) Chloride/Sodium Iodide
✍ Giuseppe Bartoli; Marcella Bosco; Armando Carlone; Manuela Locatelli; Enrico Mar πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 107 KB πŸ‘ 1 views

## Abstract The __tert__‐butoxy derivative is one of the most underused alcohol protecting groups. After having developed an easy and useful protocol for its introduction, we offer here a simple procedure for its removal by treatment with anhydrous CeCl~3~ and NaI in CH~3~CN. The procedure led to t