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Reductive transformations with trimethylsilyl chloride-sodium iodide. A new synthesis of 4H-1,3-oxazines

โœ Scribed by Eugene Ghera; Rakesh Maurya; Alfred Hassner


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
248 KB
Volume
30
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


1-Arylalkenes and l-arylalkanols are reduced to arylallcanes on heating with trimethylsilyl chloride/sodium iodide in CH&N. Under similar conditions enones, dialkylated in the Bposition of the double bond, give BH-1,3-oxazines.


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