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tert-Butyl Ethers: Renaissance of an Alcohol Protecting Group. Facile Cleavage with Cerium(III) Chloride/Sodium Iodide.

✍ Scribed by Giuseppe Bartoli; Marcella Bosco; Armando Carlone; Manuela Locatelli; Enrico Marcantoni; Paolo Melchiorre; Letizia Sambri

Publisher: John Wiley and Sons
Year: 2006
Weight: 32 KB
Volume: 37
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200637054

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✦ Synopsis

Abstract

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tert-Butyl Ethers: Renaissance of an Alc

tert-Butyl Ethers: Renaissance of an Alcohol Protecting Group. Facile Cleavage with Cerium(III) Chloride/Sodium Iodide

✍ Giuseppe Bartoli; Marcella Bosco; Armando Carlone; Manuela Locatelli; Enrico Mar 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB 👁 1 views

## Abstract The __tert__‐butoxy derivative is one of the most underused alcohol protecting groups. After having developed an easy and useful protocol for its introduction, we offer here a simple procedure for its removal by treatment with anhydrous CeCl~3~ and NaI in CH~3~CN. The procedure led to t