## Abstract The kinetics of the reactions of F and C1 atoms with ethylene oxide have been studied using relative rate techniques in 10โ700 Torr of either nitrogen or air diluent at 295 ยฑ 2 K; __k__(F + C~2~H~4~O) = (9.4 ยฑ 1.6) ร 10^โ11^ and __k__(C1 + C~2~H~4~O) = (5.0 ยฑ 0.9) ร 10^โ12^ cm^3^ molecu
Remarkable Effect of Fluorine and Chlorine Atoms on the Stability of 1H-Phosphirene
โ Scribed by Nguyen, Minh T. ;Vansweevelt, Hans ;Vanquickenborne, Luc G.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1992
- Tongue
- English
- Weight
- 443 KB
- Volume
- 125
- Category
- Article
- ISSN
- 0009-2940
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A(C2C14) kcal mole ## 9 . mole-'sec-'
Using a relative rate technique the reactions of chlorine and fluorine atoms with CF3CHO have been determined to proceed with rate constants of (1.8 % 0.4) x and (2.7 2 0.1) x lo-" cm3 molecule-' s-', respectively. Experiments were performed a t 295 ? 2 K and 700 torr total pressure of nitrogen. The