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A kinetic study of the reaction of chlorine and fluorine atoms with CF3CHO at 295 ± 2 K

✍ Scribed by T. J. Wallington; M. D. Hurley

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
362 KB
Volume
25
Category
Article
ISSN
0538-8066

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✦ Synopsis

Using a relative rate technique the reactions of chlorine and fluorine atoms with CF3CHO have been determined to proceed with rate constants of (1.8 % 0.4) x and (2.7 2 0.1) x lo-" cm3 molecule-' s-', respectively. Experiments were performed a t 295 ? 2 K and 700 torr total pressure of nitrogen. The results are discussed with respect to the design and interpretation of laboratory studies of the atmospheric chemistry of CFC replacements.

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