Kinetics of the gas-phase reaction of Cl atoms with CF2ClCFClH at 263–313 K
✍ Scribed by T. Mauer; T. J. Wallington; I. Barnes; K. H. Becker
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 101 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
Relative rate techniques were used to measure k(Cl
This result is discussed with respect to the available data.
📜 SIMILAR VOLUMES
CF 3 CF 2 CH 2 OH is a new chlorofluorocarbon (CFC) alternative. However, there are few data about its atmospheric fate. The kinetics of its atmospheric oxidation, the OH radical reaction of CF 3 CF 2 CH 2 OH, has been investigated in a 2-liter Pyrex reactor in the temperature range of 298 ϳ 356 K u
Using relative rate techniques the reactions of chlorine and fluorine atoms with HC(O)F have been determined to proceed with rate constants of and respectively. Stated errors reflect statistical uncertainty; possible systematic uncertainties could add additional 10% and 20% ranges to the values of k