The kinetics of chlorine atom abstraction from the chloromethanes (CM)CC14, CHCl3, and CHBCl2 by radiolytically generated cyclohexyl radicals has been studied in the liquid phase by a competitive method. The halogen abstraction data have been put on an absolute basis by comparing the rates of the me
Abstraction of chlorine atoms from polychloroalkanes. II. Neighboring group effect on the rates of chlorine abstraction by cyclohexyl radicals
โ Scribed by M. G. Katz; L. A. Rajbenbach
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- English
- Weight
- 486 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
โฆ Synopsis
A(C2C14) kcal mole
9
. mole-'sec-'
๐ SIMILAR VOLUMES
The kinetics of chlorine atom abstraction from the chloroethanes (EClH j 1,1,2-C2C13H3, 1, 1-CZCl2H, and 1,2-CzCl2H4 by radiolytically generated cyclohexyl radicals was studied in the liquid phase by a competitive method. The chlorine atom abstraction data were put on an absolute basis by comparing
The abstraction of hydrogen and deuterium from 1,2-dichIoroethane, 1,1,2trichloroethane, and two of their deuterated analogs by photochemically generated ground state chlorine atoms has been investigated in the temperature range 0-95ยฐC using methane as a competitor. Rate constants and their temperat