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Regioselective Iron-Catalyzed Allylic Amination.

✍ Scribed by Bernd Plietker

Publisher
John Wiley and Sons
Year
2006
Weight
27 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract Photochemical reactions between unfuctionalized olefins and nitroarenes under CO pressure, catalyzed by [Cp\*Fe(CO)~2~]~2~, form the corresponding allyl amines. The use of mechanistic probes containing 2‐nitrobiphenyl, 2,3‐dimethylbutadiene and pentafluoronitrobenzene suggest that neith