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A Highly Regioselective Salt-Free Iron-Catalyzed Allylic Alkylation.

✍ Scribed by Bernd Plietker


Publisher
John Wiley and Sons
Year
2006
Weight
31 KB
Volume
37
Category
Article
ISSN
0931-7597

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Highly Enantioselective Copper-Catalyzed
✍ Anthoniβ€…W. vanβ€…Zijl; Leggyβ€…A. Arnold; Adriaanβ€…J. Minnaard; Benβ€…L. Feringa πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 171 KB πŸ‘ 2 views

## Abstract New phosphoramidites were applied as chiral ligands in the Cu‐catalyzed allylic alkylation with dialkylzinc reagents. A variety of substrates, reagents and chiral ligands were screened, resulting in improved catalytic methodology for allylic bromides in which enantioselectivities up to