𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Regioselective Iron-Catalyzed Allylic Amination

✍ Scribed by Bernd Plietker

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
111 KB
Volume
45
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Iron-Catalyzed Ally
ChemInform Abstract: Iron-Catalyzed Allylic Amination by Nitroorganics.
✍ Radhey S. Srivastava; Kenneth M. Nicholas πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 27 KB

Iron-Catalyzed Allylic Amination by Nitroorganics. -The title reaction of olefins, e.g. (I), with nitroarenes like (II) affording regioselectively the corresponding allylamines (III) is described. A coordinated organo-nitrogen species is implicated as the active aminating agent. -(SRIVASTAVA,

Photo-induced iron-catalyzed allylic ami
Photo-induced iron-catalyzed allylic amination of unfunctionalized olefins with nitroarenes
✍ Radhey S. Srivastava πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 104 KB

## Abstract Photochemical reactions between unfuctionalized olefins and nitroarenes under CO pressure, catalyzed by [Cp\*Fe(CO)~2~]~2~, form the corresponding allyl amines. The use of mechanistic probes containing 2‐nitrobiphenyl, 2,3‐dimethylbutadiene and pentafluoronitrobenzene suggest that neith