ChemInform Abstract: Iron-Catalyzed Allylic Amination by Nitroorganics.

✍ Scribed by Radhey S. Srivastava; Kenneth M. Nicholas

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 27 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199913110

✦ Synopsis

Iron-Catalyzed Allylic Amination by Nitroorganics.

-The title reaction of olefins, e.g. (I), with nitroarenes like (II) affording regioselectively the corresponding allylamines (III) is described. A coordinated organo-nitrogen species is implicated as the active aminating agent.

-(SRIVASTAVA,