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ChemInform Abstract: Photoassisted, Iron-Catalyzed Allylic Amination of Olefins with Nitroarenes.

✍ Scribed by Radhey S. Srivastava; Manoj Kolel-Veetil; Kenneth M. Nicholas

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
33
Category
Article
ISSN
0931-7597

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## Abstract Photochemical reactions between unfuctionalized olefins and nitroarenes under CO pressure, catalyzed by [Cp\*Fe(CO)~2~]~2~, form the corresponding allyl amines. The use of mechanistic probes containing 2‐nitrobiphenyl, 2,3‐dimethylbutadiene and pentafluoronitrobenzene suggest that neith

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Iron-Catalyzed Allylic Amination by Nitroorganics. -The title reaction of olefins, e.g. (I), with nitroarenes like (II) affording regioselectively the corresponding allylamines (III) is described. A coordinated organo-nitrogen species is implicated as the active aminating agent. -(SRIVASTAVA,