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Photo-induced iron-catalyzed allylic amination of unfunctionalized olefins with nitroarenes

✍ Scribed by Radhey S. Srivastava

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 104 KB
Volume: 20
Category: Article
ISSN: 0268-2605
DOI: 10.1002/aoc.1142

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✦ Synopsis

Abstract

Photochemical reactions between unfuctionalized olefins and nitroarenes under CO pressure, catalyzed by [Cp*Fe(CO)~2~]~2~, form the corresponding allyl amines. The use of mechanistic probes containing 2‐nitrobiphenyl, 2,3‐dimethylbutadiene and pentafluoronitrobenzene suggest that neither aryl nitrene nor nitrosoarene is the active aminating agent in these transformations. Copyright © 2006 John Wiley & Sons, Ltd.

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