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Redox Control of Group 4 Metal Ring-Opening Polymerization Activity toward l -Lactide and ε-Caprolactone

✍ Scribed by Wang, Xinke; Thevenon, Arnaud; Brosmer, Jonathan L.; Yu, Insun; Khan, Saeed I.; Mehrkhodavandi, Parisa; Diaconescu, Paula L.


Book ID
126051736
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
772 KB
Volume
136
Category
Article
ISSN
0002-7863

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Polymerization of lactides and lactones.
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Ring-opening polymerization of lactone and lactide have been initiated with rare earth organoacid compounds, such as lanthanum acetate in bulk. The polymerization mechanism is in agreement with the "nonionic-coordination-insertion" mechanism, which involves the selective cleavage of the acyl-oxygen