Lanthanide Thiolate Complexes: Novel Ini
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Hong-Mei Sun; Huan-Rong Li; Chang-Sheng Yao; Ying-Ming Yao; Hong-Ting Sheng; Qi
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Article
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2005
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John Wiley and Sons
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English
⚖ 114 KB
## Abstract The ring‐opening polymerization (ROP) of __ε__‐caprolactone (__ε__‐CL) using lanthanide thiolate complexes [(CH~3~C~5~H~4~)~2~Sm(μ‐SPh)(THF)] ~2~ (1) and Sm(SPh)~3~(HMPA)~3~ (2) as initiators has been investigated for the first time. Both of 1 and 2 were found to be highly efficient ini