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Syntheses and Structures of Tris-β-Diketiminate Lanthanide Complexes and Their High Activity for Ring-Opening Polymerization of ϵ-Caprolactone and L-Lactide

✍ Scribed by Mingqiang Xue; Rui Jiao; Yong Zhang; Yingming Yao; Qi Shen


Book ID
102827026
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
525 KB
Volume
2009
Category
Article
ISSN
1434-1948

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## Abstract The ring‐opening polymerization (ROP) of __ε__‐caprolactone (__ε__‐CL) using lanthanide thiolate complexes [(CH~3~C~5~H~4~)~2~Sm(μ‐SPh)(THF)] ~2~ (1) and Sm(SPh)~3~(HMPA)~3~ (2) as initiators has been investigated for the first time. Both of 1 and 2 were found to be highly efficient ini