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Catalysts for the ring-opening polymerization of ε-caprolactone and l-lactide and the mechanistic study

✍ Scribed by Te-Liang Yu; Chen-Chang Wu; Chin-Che Chen; Bor-Hunn Huang; Jincai Wu; Chu-Chieh Lin


Book ID
108248094
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
194 KB
Volume
46
Category
Article
ISSN
0032-3861

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Mechanistic Study of Bu2SnCl2-Mediated R
✍ Gaëlle Deshayes; Frédéric A. G. Mercier; Philippe Degée; Ingrid Verbruggen; Moni 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 172 KB

## Abstract The ring‐opening polymerization (ROP) of ε‐caprolactone (CL) was carried out in toluene at 100 °C with __n__‐propanol (__n__PrOH) in the presence of Bu~2~SnCl~2~. It comes out that the molar mass of the polyester chains can be predicted from the initial monomer‐to‐alcohol molar ratio in