A Highly Efficient Initiator for the Ring-Opening Polymerization of Lactides and ε-Caprolactone: A Kinetic Study
✍ Scribed by Chen, Hsuan-Ying; Huang, Bor-Hunn; Lin, Chu-Chieh
- Book ID
- 111902992
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 304 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The ring‐opening polymerization (ROP) of ε‐caprolactone (CL) was carried out in toluene at 100 °C with __n__‐propanol (__n__PrOH) in the presence of Bu~2~SnCl~2~. It comes out that the molar mass of the polyester chains can be predicted from the initial monomer‐to‐alcohol molar ratio in