𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Polymerization of Lactides and Lactones, 8. Study on the Ring-Opening Polymerization of 3-Phenyl-ε-caprolactone and 5-Phenyl-ε-caprolactone

✍ Scribed by Xianmo Deng; Minglong Yuan; Xiaojun Cao; Xiaohong Li

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
151 KB
Volume
202
Category
Article
ISSN
1022-1352

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Polymerization of lactides and lactones.
Polymerization of lactides and lactones. IV. Ring-opening polymerization of ε-caprolactone by rare earth phenyl compounds
✍ Xianmo Deng; Minlong Yuan; Chengdong Xiong; Xiaohong Li 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 153 KB

Ring-opening polymerization of -caprolactone (CL) has been initiated with rare earth phenyl compounds in both bulk and solution. These rare earth phenyl initiators can give polycaprolactone (PCL) with high yield and high molecular weight. The polymerization mechanism is through a coordination-deprot

Polymerization of lactides and lactones.
Polymerization of lactides and lactones. II. Ring-opening polymerization of ε-caprolactone and DL-lactide by organoacid rare earth compounds
✍ X. M. Deng; M. L. Yuan; C. D. Xiong; X. H. Li 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB 👁 1 views

Ring-opening polymerization of lactone and lactide have been initiated with rare earth organoacid compounds, such as lanthanum acetate in bulk. The polymerization mechanism is in agreement with the "nonionic-coordination-insertion" mechanism, which involves the selective cleavage of the acyl-oxygen

“Coordination-insertion” ring-opening po
“Coordination-insertion” ring-opening polymerization of 1,4-dioxan-2-one and controlled synthesis of diblock copolymers with ε-caprolactone
✍ Jean-Marie Raquez; Philippe Degée; Ramani Narayan; Philippe Dubois 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB 👁 2 views

DSC thermogram of P(DX-b-CL) obtained after a polymerization time of 3.8 h (A) and 39.9 h (B) (see Tab. 2; heating rate: 10 8C/min under N 2 flow, 2 nd scan). much indebted to F.R.I.A. (Fonds pour la Formation a `la Recherche dans l'Industrie et dans l'Agriculture).

Two-Step Backbiting Reaction in the Ring
Two-Step Backbiting Reaction in the Ring-Opening Polymerization of γ-Acryloyloxy-ε-caprolactone Initiated with Aluminium Isopropoxide
✍ Xudong Lou; Christophe Detrembleur; Philippe Lecomte; Robert Jérôme 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB

Time dependence of the yields in c-acryloyloxyethyl-c-butyrolactone and poly(c-acryloyloxy-e-caprolactone) in toluene at 0 8C. Conditions: [ACL] 0 = 1 m, [ACL] 0 /[Al(O i Pr) 3 ] 0 = 50 (ACL: c-acryloyloxy-e-caprolactone). Scheme 1.

Polymerization of lactides and lactones.
Polymerization of lactides and lactones. III. Ring-opening polymerization of DL-lactide by the (η3-C3H5)2Sm(μ2-Cl)2(μ3-Cl)2Mg(tmed)(μ2-Cl)Mg(tmed) complex
✍ Minlong Yuan; Chengdong Xiong; Xiaohong Li; Xianmo Deng 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 197 KB

Ring-opening polymerization of DL-lactide (LA) has been initiated with the ( 3 -C 3 H 5 ) 2 Sm( 2 -Cl) 2 ( 3 -Cl) 2 Mg(tmed)( 2 -Cl)Mg(tmed) complex both in bulk and solution. The effects of reaction conditions, such as reaction time, reaction temperature, and monomer/initiator molar ratio on the po