✦ LIBER ✦

Two-Step Backbiting Reaction in the Ring-Opening Polymerization of γ-Acryloyloxy-ε-caprolactone Initiated with Aluminium Isopropoxide

✍ Scribed by Xudong Lou; Christophe Detrembleur; Philippe Lecomte; Robert Jérôme

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 96 KB
Volume: 23
Category: Article
ISSN: 1022-1336
DOI: 10.1002/1521-3927(20020101)23:2<126::aid-marc126>3.0.co;2-t

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✦ Synopsis

Time dependence of the yields in c-acryloyloxyethyl-c-butyrolactone and poly(c-acryloyloxy-e-caprolactone) in toluene at 0 8C. Conditions: [ACL] 0 = 1 m, [ACL] 0 /[Al(O i Pr) 3 ] 0 = 50 (ACL: c-acryloyloxy-e-caprolactone).

Scheme 1.