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Ring-Opening Polymerization of ε-Caprolactone and l -Lactide Using Aluminum Thiolates as Initiator

✍ Scribed by Huang, Ching-Huei; Wang, Fa-Cherng; Ko, Bao-Tsan; Yu, Te-Liang; Lin, Chu-Chieh

Book ID
121183141
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
79 KB
Volume
34
Category
Article
ISSN
0024-9297

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Lanthanide Thiolate Complexes: Novel Ini
Lanthanide Thiolate Complexes: Novel Initiators for Ring-opening Polymerization of ε-Caprolactone
✍ Hong-Mei Sun; Huan-Rong Li; Chang-Sheng Yao; Ying-Ming Yao; Hong-Ting Sheng; Qi 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB

## Abstract The ring‐opening polymerization (ROP) of __ε__‐caprolactone (__ε__‐CL) using lanthanide thiolate complexes [(CH~3~C~5~H~4~)~2~Sm(μ‐SPh)(THF)] ~2~ (1) and Sm(SPh)~3~(HMPA)~3~ (2) as initiators has been investigated for the first time. Both of 1 and 2 were found to be highly efficient ini