## Abstract Ethenic alcohols, ethynic tertiary alcohols, hydroxy ethers, cyclic alcohols, araliphatic alcohols, and phenol react very easily with phenyl phosphonic oxide to yield the corresponding phosphonic monoesters.
Recherches sur la formation et la transformation des esters XXX. Sur l'action de l'oxyde phénylphosphonique sur les amines et les amino-alcools
✍ Scribed by Emile Cherbuliez; Br. Baehler; J. Rabinowitz
- Publisher
- John Wiley and Sons
- Year
- 1961
- Tongue
- German
- Weight
- 324 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
The reaction of phenylphosphonic oxide with amines and amino‐alcools is described. Under appropriate conditions this reaction yields respectively the corresponding phosphonic mono‐amides and mono‐esters.
📜 SIMILAR VOLUMES
Phenylphosphonic oxide reacts with halogenated alcohols to give the corresponding halogenoalkyl phenylphosphonic monoesters in very good yields.
Phenylphosphonic oxide reacts with diols to give the corresponding hydroxyalkylphenylphosphonic monoesters in very good yields.
## Abstract The phosphonylation of cyano alcohols by means of phenylphosphonic oxide is described. α‐Cyano alcohols yield exclusively the corresponding α‐carbamidoalkyl phenylphosphonic monoesters, β‐cyano alcohols yield mainly the corresponding β‐cyanoalkyl phenylphosphonic monoesters, and γ‐ and
Treated with a primary or secondary alcohol, phenylphosphonic oxide (C~6~H~5~PO~2~)~n~ gives the corresponding phosphonic monoesters in very good yield.
Par halolyse des esters, nous entendons la rBaction suivante: ester de l'acide I + sel de I'acide I1ester de I'acide I1 + sel de I'acide I. L'intervention de cette reaction B titre de processus distinct a BtB montree notamment dans le cas de la scission des esters phos-phoriques2), ou elle se produ