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Recherches sur la formation et la transformation des esters XXXIX. Sur la phosphonylation des hydroxynitriles par l'oxyde phénylphosphonique

✍ Scribed by Emile Cherbuliez; F. Hunkeler; J. Rabinowitz

Publisher: John Wiley and Sons
Year: 1962
Tongue: German
Weight: 292 KB
Volume: 45
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19620450738

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✦ Synopsis

Abstract

The phosphonylation of cyano alcohols by means of phenylphosphonic oxide is described. α‐Cyano alcohols yield exclusively the corresponding α‐carbamidoalkyl phenylphosphonic monoesters, β‐cyano alcohols yield mainly the corresponding β‐cyanoalkyl phenylphosphonic monoesters, and γ‐ and δ‐cyano alcohols yield exclusively the corresponding γ and δ‐cyanoalkyl phenylphosphonic monoesters.

📜 SIMILAR VOLUMES

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Recherches sur la formation et la transformation des esters XXXI. Sur la phosphonylation des diols par l'oxyde phénylphosphonique

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Phenylphosphonic oxide reacts with diols to give the corresponding hydroxyalkylphenylphosphonic monoesters in very good yields.

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Recherches sur la formation et la transformation des esters XXVIII. Sur la phosphonylation d'alcools halogénés par l'oxyde phénylphosphonique

✍ Emile Cherbuliez; Br. Baehler; F. Hunkeler; J. Rabinowitz 📂 Article 📅 1961 🏛 John Wiley and Sons 🌐 German ⚖ 171 KB

Phenylphosphonic oxide reacts with halogenated alcohols to give the corresponding halogenoalkyl phenylphosphonic monoesters in very good yields.

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Recherches sur la formation et la transformation des esters XLV. Sur la phosphonylation des hydroxyacides, des hydroxynitriles et des hydroxyesters

✍ Emile Cherbuliez; Sl. Čolak-Antić; F. Hunkeler; J. Rabinowitz 📂 Article 📅 1963 🏛 John Wiley and Sons 🌐 German ⚖ 345 KB

## Abstract Carboxy‐alkyl phenylphosphonic monoesters are obtained very easily by selective hydrolysis (in alcaline medium) of the corresponding carbamido‐ or cyano‐alkyl phenylphosphonic monoesters and sometimes of the corresponding carbethoxy‐alkyl phenylphosphonic monoesters and sometimes of the

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Recherches sur la formation et la transformation des esters XL. Sur la phosphonylation d'alcools divers par l'oxyde p-fluorophénylphosphonique

✍ Emile Cherbuliez; G. Weber; J. Rabinowitz 📂 Article 📅 1962 🏛 John Wiley and Sons 🌐 German ⚖ 278 KB

## Abstract __p__‐Fluorophenyl phosphonic oxide reacts with different type of alcohols, and with tertiary alcohols in the presence of a tertiary base, to yield the corresponding __p__‐fluorophenyl phosphonic monoesters.

Recherches sur la formation et la transf

Recherches sur la formation et la transformation des esters XXVIII. Sur la phosphonylation des alcools par les oxydes phosphoniques

✍ Emile Cherbuliez; Br. Baehler; F. Hunkeler; J. Rabinowitz 📂 Article 📅 1961 🏛 John Wiley and Sons 🌐 German ⚖ 225 KB

Treated with a primary or secondary alcohol, phenylphosphonic oxide (C~6~H~5~PO~2~)~n~ gives the corresponding phosphonic monoesters in very good yield.

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Recherches sur la formation et la transformation des esters XXX. Sur l'action de l'oxyde phénylphosphonique sur les amines et les amino-alcools

✍ Emile Cherbuliez; Br. Baehler; J. Rabinowitz 📂 Article 📅 1961 🏛 John Wiley and Sons 🌐 German ⚖ 324 KB

The reaction of phenylphosphonic oxide with amines and amino‐alcools is described. Under appropriate conditions this reaction yields respectively the corresponding phosphonic mono‐amides and mono‐esters.