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Recherches sur la formation et la transformation des esters XLIV. Sur l'action de l'oxyde phénylphosphonique sur des alcools non saturés, des hydroxy-éthers, des alcools cycliques et le phénol

✍ Scribed by Emile Cherbuliez; Sl. Čolak-Antić; A. Gabbai; F. Hunkeler; M. Gowhari; J. Rabinowitz


Publisher
John Wiley and Sons
Year
1963
Tongue
German
Weight
315 KB
Volume
46
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Ethenic alcohols, ethynic tertiary alcohols, hydroxy ethers, cyclic alcohols, araliphatic alcohols, and phenol react very easily with phenyl phosphonic oxide to yield the corresponding phosphonic monoesters.


📜 SIMILAR VOLUMES


Recherches sur la formation et la transf
✍ Emile Cherbuliez; Br. Baehler; J. Rabinowitz 📂 Article 📅 1961 🏛 John Wiley and Sons 🌐 German ⚖ 324 KB

The reaction of phenylphosphonic oxide with amines and amino‐alcools is described. Under appropriate conditions this reaction yields respectively the corresponding phosphonic mono‐amides and mono‐esters.

Recherches sur la formation et la transf
✍ Emile Cherbuliez; F. Hunkeler; J. Rabinowitz 📂 Article 📅 1962 🏛 John Wiley and Sons 🌐 German ⚖ 292 KB

## Abstract The phosphonylation of cyano alcohols by means of phenylphosphonic oxide is described. α‐Cyano alcohols yield exclusively the corresponding α‐carbamidoalkyl phenylphosphonic monoesters, β‐cyano alcohols yield mainly the corresponding β‐cyanoalkyl phenylphosphonic monoesters, and γ‐ and

Recherches sur la formation et la transf
✍ Emile Cherbuliez; R. Prince; J. Rabinowitz 📂 Article 📅 1964 🏛 John Wiley and Sons 🌐 German ⚖ 416 KB

Menthol, unsaturated alcohols, and cyano alcohols are very easily esterified by phosphorous acid and yield the corresponding phosphorous monoesters. u-Cyano alcohols yield the corresponding carbamidoalkylphosphorous monoesters, whereas p, y , etc. cyano alcohols yield mixtures containing the corres

Recherches sur la formation et la transf
✍ Emile Cherbuliez; G. Weber; J. Rabinowitz 📂 Article 📅 1962 🏛 John Wiley and Sons 🌐 German ⚖ 278 KB

## Abstract __p__‐Fluorophenyl phosphonic oxide reacts with different type of alcohols, and with tertiary alcohols in the presence of a tertiary base, to yield the corresponding __p__‐fluorophenyl phosphonic monoesters.