The reaction of phenylphosphonic oxide with amines and amino‐alcools is described. Under appropriate conditions this reaction yields respectively the corresponding phosphonic mono‐amides and mono‐esters.
Recherches sur la formation et la transformation des esters XLIV. Sur l'action de l'oxyde phénylphosphonique sur des alcools non saturés, des hydroxy-éthers, des alcools cycliques et le phénol
✍ Scribed by Emile Cherbuliez; Sl. Čolak-Antić; A. Gabbai; F. Hunkeler; M. Gowhari; J. Rabinowitz
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- German
- Weight
- 315 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
Ethenic alcohols, ethynic tertiary alcohols, hydroxy ethers, cyclic alcohols, araliphatic alcohols, and phenol react very easily with phenyl phosphonic oxide to yield the corresponding phosphonic monoesters.
📜 SIMILAR VOLUMES
Phenylphosphonic oxide reacts with halogenated alcohols to give the corresponding halogenoalkyl phenylphosphonic monoesters in very good yields.
Phenylphosphonic oxide reacts with diols to give the corresponding hydroxyalkylphenylphosphonic monoesters in very good yields.
## Abstract The phosphonylation of cyano alcohols by means of phenylphosphonic oxide is described. α‐Cyano alcohols yield exclusively the corresponding α‐carbamidoalkyl phenylphosphonic monoesters, β‐cyano alcohols yield mainly the corresponding β‐cyanoalkyl phenylphosphonic monoesters, and γ‐ and
Menthol, unsaturated alcohols, and cyano alcohols are very easily esterified by phosphorous acid and yield the corresponding phosphorous monoesters. u-Cyano alcohols yield the corresponding carbamidoalkylphosphorous monoesters, whereas p, y , etc. cyano alcohols yield mixtures containing the corres
## Abstract __p__‐Fluorophenyl phosphonic oxide reacts with different type of alcohols, and with tertiary alcohols in the presence of a tertiary base, to yield the corresponding __p__‐fluorophenyl phosphonic monoesters.