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Reactions of tris(trimethylsilyl)silyl radicals with nitro alkanes. EPR, kinetic, and product studies

โœ Scribed by Ballestri, Marco; Chatgilialoglu, Chryssostomos; Lucarini, Marco; Pedulli, Gian Franco


Book ID
125930542
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
588 KB
Volume
57
Category
Article
ISSN
0022-3263

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Kinetic studies of the reactions of CN r
โœ B. Atakan; J. Wolfrum ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 407 KB

Absolute rate coefficients for the reaction of CN radicals with methane (k,), ethane (kz) and propane ( kJ) were measured as a function of temperature in a heatable quartz reactor by means of a laser photolysis/laser-induced fluorescence (LP/LIF) technique. CN was generated by 193 nm photolysis of c