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ChemInform Abstract: Addition Reactions of Tris(trimethylsilyl)germyl Radicals to Unsaturated Compounds. An EPR and Product Study.

✍ Scribed by S. BERNARDONI; M. LUCARINI; G. F. PEDULLI; L. VALGIMIGLI; V. GEVORGYAN; C. CHATGILIALOGLU


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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## Abstract The L‐valine based thiourea VTU catalyzes the reaction of nitromethane with chalcones with up to 90% enantioselectivities, whereas ketones such as (Ih)‐(Ij) give only low enantioselectivities.