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Silicon-carbon bond formation kinetics: study of the reactions of methyl with silyl, trimethylsilyl, and trichlorosilyl

✍ Scribed by Niiranen, Jukka T.; Gutman, David


Book ID
127079051
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
612 KB
Volume
97
Category
Article
ISSN
0022-3654

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Carbon–hydrogen bond strengths in methyl
✍ Richard K. Solly; Sidney W. Benson πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 507 KB

The gas phase reaction I, + HCOOCH, +HI + CH,I + CO, has been studied spectrophotometrically in a static system over the pressure ranges I, (6-39 torr) and HCOOMe (28-360 torr). In the temperature range 293-356', the initial rate of disappearance of I, is first order in [HCOOMe] and half-order in [I