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Addition Reactions of Tris(trimethylsilyl)germyl Radicals to Unsaturated Compounds. An EPR and Product Study

โœ Scribed by Bernardoni, Stefania; Lucarini, Marco; Pedulli, Gian Franco; Valgimigli, Luca; Gevorgyan, Vladimir; Chatgilialoglu, Chryssostomos


Book ID
127257830
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
274 KB
Volume
62
Category
Article
ISSN
0022-3263

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โœ Edward G. Janzen; Uwe M. Oehler ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 231 KB

Persistent cyclic acyloxy aminoxyl radicals can be obtained by intramolecular trapping of benzoyl radicals by adjacent aromatic nitro groups whereas analogous intermolecular acyloxy adducts decay by N-O cleavage to give C-nitroso compounds and ultimately acyl aminoxyls. Iwamura and Inamoto' were se