✦ LIBER ✦
An ESR and ENDOR study of intramolecular and intermolecular addition reactions of benzoyl and substituted benzoyl radicals to nitroaromatic compounds. A two-step oxygen atom abstraction reaction.
✍ Scribed by Edward G. Janzen; Uwe M. Oehler
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 231 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Persistent cyclic acyloxy aminoxyl radicals can be obtained by intramolecular trapping of benzoyl radicals by adjacent aromatic nitro groups whereas analogous intermolecular acyloxy adducts decay by N-O cleavage to give C-nitroso compounds and ultimately acyl aminoxyls.
Iwamura and Inamoto' were searching for an oxygen abstraction reaction in the thermal decom-