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Reactions of Substituted Boryl Radicals with Nitroalkanes. EPR, Kinetic, and Product Studies

โœ Scribed by Lucarini, Marco; Pedulli, Gian Franco; Valgimigli, Luca

Book ID
126475522
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
241 KB
Volume
61
Category
Article
ISSN
0022-3263

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โœ G. Le Bras; J. Combourieu ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 452 KB ๐Ÿ‘ 2 views

Reactions of CFSBr with H atoms and OH radicals have been studied a t room temperature a t 1-2 torr pressures in a discharge flow reactor coupled to an EPR spectrometer. The rate constant of the reaction H + CF3Br -CF3 + HBr (1) was found to be k l = (3.27 f 0.34) X cm:'/moleesec was determined for