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Reaction of Methyl Bromide with Dimethylformamide

✍ Scribed by Neumeyer, J. L.; Cannon, J. G.

Book ID: 127000209
Publisher: American Chemical Society
Year: 1961
Tongue: English
Weight: 266 KB
Volume: 26
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01069a507

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## Abstract The reactivity of the lithium halides in 83.3% pyridine‐dimethylformamide changes from Cl^−^ > Br^−^ > I^−^ to Br^−^ > I^−^ to Br^−^ > I^−^ > Cl^−^ with increasing concentration of the salt from 0 to 0.35 M. This behaviour is explained by ion pairing which reduces the concentration of r