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612. Reactions of polyfluoroaryl bromides with cuprous salts in dimethylformamide

โœ Scribed by Belf, L. J. ;Buxton, M. W. ;Fuller, G.

Book ID
120075873
Publisher
The Royal Society of Chemistry
Year
1965
Weight
814 KB
Category
Article
ISSN
0368-1769

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Kinetics and mechanism of the reaction o
Kinetics and mechanism of the reaction of substituted benzyl bromides with copper in dimethylformamide
โœ Anatoly M. Egorov; Svetlana A. Matyukhova; Alexander V. Anisimov ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 182 KB ๐Ÿ‘ 1 views

The reaction of copper metal with various substituted benzyl bromides in dimethylformamide has been studied and the kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log(k/k โ€ข ) vs the substituent constant ฯƒ gave good correlations (ฯ = 0.24, S ฯ = 0.03, r = 0.