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Kinetics and Mechanism of the Reaction of Benzyl Bromide with Titanium in Dimethylformamide

โœ Scribed by A. M. Egorov; S. A. Matyukhova; N. V. Uvarova; A. V. Anisimov


Publisher
Springer
Year
2005
Tongue
English
Weight
63 KB
Volume
75
Category
Article
ISSN
1070-3632

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๐Ÿ“œ SIMILAR VOLUMES


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โœ Anatoly M. Egorov; Svetlana A. Matyukhova; Alexander V. Anisimov ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 182 KB ๐Ÿ‘ 1 views

The reaction of copper metal with various substituted benzyl bromides in dimethylformamide has been studied and the kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log(k/k โ€ข ) vs the substituent constant ฯƒ gave good correlations (ฯ = 0.24, S ฯ = 0.03, r = 0.

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## Abstract The reaction of copper with benzyl bromides in hexamethylphosphoramide has been studied. The kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log (__k__/__k__^o^) vs the substituent constant ฯƒ gave good correlations (ฯ = 0.15, __S__~ฯ~ = 0.02, __

Kinetics and mechanism of the reaction b
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The kinetics of oxidation of N,N-dimethylformamide by chromium(VI) has been studied spectrophotometrically in aqueous perchloric acid media at 20ะŠC. The rate showed a first-order dependence on both [Cr(VI)] and [DMF], and increased markedly with increasing [H ฯฉ ]. The order with respect to [HClO 4 ]

The kinetics of reaction of copper with
โœ Anatoly M. Egorov; Svetlana A. Matyukhova; Alexander V. Anisimov ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 233 KB

## Abstract The reaction of copper with benzyl bromides in dipolar aprotic solvents has been studied. There are no linear or other simple relations between ฮต, 1/ฮต, __Y__, __P__, __n__, and the rate of reaction. The activity of the solvent is determined by donor number (DN) in reaction under conside