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Reaction of Benzyl Bromide with Mn(0) in Dimethylformamide

โœ Scribed by A. M. Egorov; S. A. Matyukhova; Yu. A. Nikishova; V. V. Platonov; V. A. Proskuryakov


Publisher
SP MAIK Nauka/Interperiodica
Year
2005
Tongue
English
Weight
71 KB
Volume
78
Category
Article
ISSN
1070-4272

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## Abstract The reaction of copper with benzyl bromides in hexamethylphosphoramide has been studied. The kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log (__k__/__k__^o^) vs the substituent constant ฯƒ gave good correlations (ฯ = 0.15, __S__~ฯ~ = 0.02, __