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Kinetics and mechanism of nickel reaction with benzyl bromide in dimethylformamide

โœ Scribed by A. M. Egorov; S. A. Matyukhova; I. S. Kocherova; A. A. Novikova; A. V. Anisimov

Book ID
111460017
Publisher
Springer
Year
2009
Tongue
English
Weight
222 KB
Volume
79
Category
Article
ISSN
1070-3632

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The reaction of copper metal with various substituted benzyl bromides in dimethylformamide has been studied and the kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log(k/k โ€ข ) vs the substituent constant ฯƒ gave good correlations (ฯ = 0.24, S ฯ = 0.03, r = 0.

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## Abstract The reaction of copper with benzyl bromides in hexamethylphosphoramide has been studied. The kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log (__k__/__k__^o^) vs the substituent constant ฯƒ gave good correlations (ฯ = 0.15, __S__~ฯ~ = 0.02, __