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Kinetics and mechanism of benzyl chloride reaction with zinc in dimethylacetamide

✍ Scribed by Egorov, A. M.; Matyukhova, S. A.; Dashkova, E. A.

Book ID
118725595
Publisher
Springer
Year
2012
Tongue
English
Weight
327 KB
Volume
82
Category
Article
ISSN
1070-3632

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## Abstract The reaction of copper with benzyl bromides in hexamethylphosphoramide has been studied. The kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log (__k__/__k__^o^) vs the substituent constant Οƒ gave good correlations (ρ = 0.15, __S__~ρ~ = 0.02, __