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Rate parameters for the reactions of the bromomethyne radical

✍ Scribed by R.S. McDaniel; Ross Dickson; F.C. James; O.P. Strausz; T.N. Bell

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 417 KB
Volume: 43
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80774-9

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✦ Synopsis

Absolute rate paramctcrs wcrc mtiasured for the gas phase reactions of CBr(% '11) produced in the flash photolysis of CHBr3 with a variety of paraffins, olcfins. 0:: and NO. The rate of cyclaaddition to unsaturated bonds increases with alkyl substitution, pointing to the clcctrophilic nature of CBr. In comparison with published data on CC1 and CH the reactivity follows the trend CBr = CCI < CH.

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