✦ LIBER ✦

Rate constants for the reaction of the bromomethyne radical with alkynes

✍ Scribed by F.C. James; B. Ruzsicska; R.S. McDaniel; R. Dickson; O.P. Strausz; T.N. Bell

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 379 KB
Volume: 45
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80061-4

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Rate parameters for the reactions of the

Rate parameters for the reactions of the bromomethyne radical

✍ R.S. McDaniel; Ross Dickson; F.C. James; O.P. Strausz; T.N. Bell 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 417 KB

Absolute rate paramctcrs wcrc mtiasured for the gas phase reactions of CBr(% '11) produced in the flash photolysis of CHBr3 with a variety of paraffins, olcfins. 0:: and NO. The rate of cyclaaddition to unsaturated bonds increases with alkyl substitution, pointing to the clcctrophilic nature of CBr.

Rate constants for the reactions of O3 a

Rate constants for the reactions of O3 and OH radicals with a series of alkynes

✍ Roger Atkinson; Sara M. Aschmann 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 499 KB 👁 1 views

Rate constants for the reactions of 0, and OH radicals with acetylene, propyne, and 1-butyne have been determined at room temperature. The rate constants obtained a t 294 i 2 K for the reactions of 0, with acetylene, propyne, and 1-butyne were (7.8 -c 1.2) x lo-'' cm3/molecule . s, (1.43 2 0.15) x l

Absolute rate constant for the reaction

Absolute rate constant for the reaction of Phenyl radical with Acetylene

✍ T. Yu; M. C. Lin; C. F. Melius 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 490 KB 👁 1 views

The absolute rate constant for the reaction of phenyl radical with acetylene has been measured at 20 torr total pressure in the temperature range of 297 to 523 K using the cavity-ring-down technique. These new kinetic data could be quantitatively correlated with the data obtained earlier with a rela

Rate constant for the reaction of OH rad

Rate constant for the reaction of OH radicals with dimethyl sulfide

✍ Yen-Chung Hsu; Dze-Shu Chen; Yuan-Pern Lee 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 485 KB 👁 2 views

The rate constants of the gas phase reaction of OH radicals with dimethyl sulfide (CH3SCH3) over the temperature range 260-393 K have been studied using the discharge flow-resonance fluorescence technique. The rate constants were fitted by the Arrhenius equation k = (11.8 2 2.2) x exp[-(236 2 150)/T

Rate constants for reactions of perfluor

Rate constants for reactions of perfluorobutylperoxyl radical with alkenes

✍ G. S. Nahor; P. Neta 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 334 KB

Perfluorobutylperoxyl radicals were produced by radiolytic reduction of perf luorobutyl iodide in aerated methanol solutions. Rate constants for the reactions of this peroxyl radical with various organic compounds were determined by kinetic spectrophotometric pulse radiolysis. The rate constants for

Rate constants for the reactions of OH r

Rate constants for the reactions of OH radicals with alkyl substituted olefins

✍ Tomohiro Ohta 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 417 KB 👁 2 views

Relative rate constants for the reactions of hydroxyl radicals with a series of alkyl substituted olefins were measured by competitive reactions between pairs of olefins a t 298 r 2 K and 1 atmospheric pressure. Hydroxyl radicals were produced by the photolysis of H,O, with 254-nm irradiation. The o