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Rate Enhancement of Diels−Alder Reactions in Aqueous Perfluorinated Emulsions

✍ Scribed by Nishimoto, Kohsuke; Kim, Shokaku; Kitano, Yoshikazu; Tada, Masahiro; Chiba, Kazuhiro

Book ID
118165978
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
143 KB
Volume
8
Category
Article
ISSN
1523-7060

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✍ Paul A. Grieco; Philip Garner; Zhen-min He 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 192 KB

The intermolecular Diels-Alder reactions employing dienophiles k and 2 with diene < have been examined in water. The significantly enhanced rates, as well as the improved selectivity observed in water stand in sharp contrast to the results observed in hydrocarbon solvents: