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Rate Enhancement in Dilute Salt Solutions of Aqueous Ethanol: The Diels-Alder Reaction

โœ Scribed by Pai, Chaitanya K.; Smith, Michael B.


Book ID
126002400
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
701 KB
Volume
60
Category
Article
ISSN
0022-3263

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The intermolecular Diels-Alder reactions employing dienophiles k and 2 with diene < have been examined in water. The significantly enhanced rates, as well as the improved selectivity observed in water stand in sharp contrast to the results observed in hydrocarbon solvents: