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Rate Enhancement of Diels—Alder Reactions in Aqueous Perfluorinated Emulsions.

✍ Scribed by Kohsuke Nishimoto; Shokaku Kim; Yoshikazu Kitano; Masahiro Tada; Kazuhiro Chiba


Publisher
John Wiley and Sons
Year
2007
Weight
27 KB
Volume
38
Category
Article
ISSN
0931-7597

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✍ Gérard Jenner 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 90 KB 👁 2 views

The kinetic pressure effect on some Michael-like and [4 2] cycloadditions in aqueous solution was studied. This effect is complex and variable, in contrast to the pressure dependence of rate constants in organic solvents. In order to determine the origin of this kinetic behavior, systematic solvent