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Hydrophobic and Hydrogen-Bonding Effects on the Rate of Diels−Alder Reactions in Aqueous Solution

✍ Scribed by Furlani, Thomas R.; Gao, Jiali

Book ID
126771740
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
134 KB
Volume
61
Category
Article
ISSN
0022-3263

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Kinetic effect of pressure on Michael an
Kinetic effect of pressure on Michael and Diels–Alder reactions in aqueous solutions
✍ Gérard Jenner 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 90 KB 👁 2 views

The kinetic pressure effect on some Michael-like and [4 2] cycloadditions in aqueous solution was studied. This effect is complex and variable, in contrast to the pressure dependence of rate constants in organic solvents. In order to determine the origin of this kinetic behavior, systematic solvent